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Highly Toxic Chemical to be
Phased Out at Valero Refinery

Feb. 7, 2003

As Part of Environmental Justice Initiatives

Southland air quality officials today approved an enforceable agreement with the Valero oil refinery in Wilmington to phase out the facility’s use of the toxic chemical hydrogen fluoride by 2006.

“Once this refinery stops using concentrated hydrogen fluoride, we will have virtually eliminated the potential for a catastrophic accidental release of this compound in our region,” said Barry Wallerstein, executive officer of the South Coast Air Quality Management District.

“We commend Valero for voluntarily phasing out this chemical, which will significantly increase the safety of thousands of residents living near this refinery,” he said.

The agreement fulfils one of the 23 Environmental Justice goals adopted by AQMD’s Governing Board last fall.

Hydrogen fluoride (HF) is a pungent, highly corrosive acid used at oil refineries in a process called alkylation that boosts gasoline octane.  HF also is used at chemical plants to manufacture compounds including refrigerants.

The chemical poses a risk to nearby residents and businesses because in the event of an accidental release, it can form a dense, fuming cloud capable of etching glass and causing severe damage to human skin and lung tissue.

In 1987, an accidental release of HF resulted from an explosion at the Mobil refinery in Torrance.  The same year, there was an accidental HF release at the Marathon Oil refinery in Texas City, Texas.

Under terms of the agreement, the Valero facility, also known as the Ultramar refinery, will:

  • Replace its use of HF by Dec. 31, 2005, with modified HF, which contains additives that significantly reduce the chemical’s ability to form a vapor cloud in the event of an accidental release;
  • Enhance its existing safety systems to minimize the impact of an accidental HF release; and
  • Pay a penalty of $1 million if it fails to meet the deadline for phasing out HF, barring unforeseen circumstances.

In addition, if for any reason Valero does not phase out its use of HF, AQMD will seek to expeditiously adopt a rule requiring them to do so.

The Valero facility will undergo significant construction to switch to modified HF.  AQMD has pledged to expedite the processing of air quality permits needed for the construction.

Switching to modified HF will minimize the possibility of a catastrophic accidental release not only at the refinery, but along Southland transportation corridors, as the additive is added to the chemical before shipping.

HF History

In the late 1980s, four oil refineries and one chemical plant in the Southland used HF.  Following the 1987 accidental release of HF in Torrance, AQMD formed a task force and the agency’s Governing Board adopted Rule 1410 in 1991 to phase out the use of HF by 1998.  The rule was challenged in court by industry and a Superior Court judge suspended the rule on a technicality in 1992.

Since then, two of the refineries using HF have shut down, one has voluntarily switched to modified HF and the chemical plant has phased out its HF use, leaving the Valero refinery as the only facility in the region still using the hazardous chemical.

AQMD is the air pollution control agency for Orange County and major portions of Los Angeles, San Bernardino and Riverside counties.

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